The Activation Mechanism of Ru-Indenylidene Complexes in Olefin Metathesis

​
​ ​ ​ ​
Urbina-Blanco, Cesar A.
orcId Poater Teixidor, Albert​ researcherId Poater Teixidor, Albert​ scopusId Poater Teixidor, Albert​ ​
Poater Teixidor, Albert
​ ​ ​ ​
Lebl, Tomas
​ ​ ​ ​
Manzini, Simone
​ ​ ​ ​
Slawin, Alexandra M. Z.
​ ​ ​ ​
Cavallo, Luigi
​ ​ ​ ​
Nolan, Steven P.
Texto Completo
ActivationMechanism.pdf embargoed access ​
Solicita copia
Solicita copia
Al rellenar este formulario estáis solicitando una copia del artículo, depositado en el repositorio institucional (DUGiDocs), a su autor o al autor principal del artículo. Será el mismo autor quien decidirá enviar una copia del documento a quien lo solicite si lo considera oportuno. En todo caso, la Biblioteca de la UdG no interviene en este proceso ya que no está autorizada a facilitar artículos cuando éstos son de acceso restringido.
​
Compartir
​
Olefin metathesis is a powerful tool for the formation of carbon-carbon double bonds. Several families of well-defined ruthenium (Ru) catalysts have been developed during the past 20 years; however, the reaction mechanism for all such complexes was assumed to be the same. In the present study, the initiation mechanism of Ru-indenylidene complexes was examined and compared with that of benzylidene counterparts. It was discovered that not all indenylidene complexes followed the same mechanism, highlighting the importance of steric and electronic properties of so-called spectator ligands, and that there is no single mechanism for the Ru-based olefin metathesis reaction. The experimental findings are supported quantitatively by DFT calculations ​
​Tots els drets reservats
Mostrar el registro completo del ítem