DUGiDocsNicht in jedem Punkt schuldig: Der “nicht‐unschuldige” Nitrosyl‐Ligand in IUPACs Oxidationsstufen‐Empfehlung
dc.contributor.author
dc.date.accessioned
2021-05-13T12:00:23Z
dc.date.available
2021-05-13T12:00:23Z
dc.date.issued
2020-07-20
dc.identifier.issn
0044-8249
dc.identifier.uri
dc.description
Aquest mateix article està publicat en anglès a: 'Angewandte Chemie International Edition' (ISSN 1433-7851, EISSN 1521-3773), 2020, vol. 59, núm. 30, p. 12381-12386. DOI https://doi.org/10.1002/anie.202003122
Publisher Note for articles published since 1962: This is the German version of Angewandte Chemie. Do not cite this version alone. Take the reference of the International Edition version
dc.description.abstract
Nitrosyl–metal bonding relies on the two interactions between the pair of N–O‐π* and two of the metal's d orbitals. These (back)bonds are largely covalent, which makes their allocation in the course of an oxidation‐state determination ambiguous. However, apart from M‐N‐O‐angle or net‐charge considerations, IUPAC′s “ionic approximation” is a useful tool to reliably classify nitrosyl metal complexes in an orbital‐centered approach
The MNO segment should be linear for NO+ but bent for NO−“: Diese Aussage entstammt zwar einer IUPAC‐Publikation zu Oxidationstufen (OS), spiegelt zugleich aber eine verbreitete Meinung wider. Die Herleitung der OS durch den EOS‐Algorithmus führt jedoch für eine neue Nitrosylcobalt‐Spezies (siehe Bild) zu einem CoI(NO+)‐Paar anstelle der erwarteten CoIII(NO−)‐Formulierung
dc.description.sponsorship
Deutsche Forschungsgemeinschaft. Grant Number: KL 624/18-1 Ministerio de Ciencia, Innovación y Universidades. Grant Number: PGC2018-098212-B-C22
dc.format.mimetype
application/pdf
dc.language.iso
deu
dc.publisher
Wiley
dc.relation
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-098212-B-C22/ES/DESCOMPOSICION EN EL ESPACIO REAL DE PROPIEDADES OPTICAS NO LINEALES PARA EL DISEÑO RACIONAL DE MATERIALES OPTOELECTRONICOS/
dc.relation.isformatof
Reproducció digital del document publicat a: https://doi.org/10.1002/ange.202003122
dc.relation.ispartof
Angewandte Chemie, 2020, vol. 132, núm. 30, p. 12480-12485
dc.relation.ispartofseries
Articles publicats (D-Q)
dc.relation.uri
dc.rights
Attribution 4.0 International
dc.rights.uri
dc.subject
dc.title
Nicht in jedem Punkt schuldig: Der “nicht‐unschuldige” Nitrosyl‐Ligand in IUPACs Oxidationsstufen‐Empfehlung
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.contributor.funder
dc.type.peerreviewed
peer-reviewed
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
1521-3757