DUGiDocsOlefin-Dependent Discrimination Between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations
dc.contributor.author
dc.date.accessioned
2019-05-06T12:01:36Z
dc.date.available
2019-05-06T12:01:37Z
dc.date.issued
2009-03-23
dc.identifier.issn
0947-6539
dc.identifier.uri
dc.description.abstract
Wet oxygenase models: Unprecedented high levels of water incorporation into products (up to 75 %) is observed in epoxidation reactions with H2O2 by a bioinspired nonheme iron catalyst. A surprising substrate‐dependent incorporation of water is observed, and is proposed to arise from fast equilibrium between two high‐valent HOFeVO isomeric species exhibiting different reactivity
dc.description.sponsorship
Financial support from MCYT of Spain through project CTQ2006–05367/BQU to M.C., and from the US Department of Energy (DE‐FG02–03ER15455) to L.Q. is gratefully acknowledged
dc.format.extent
4 p.
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application/pdf
dc.language.iso
eng
dc.publisher
Wiley
dc.relation
MEC/PN 2006-2009/CTQ2006-05367
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Versió postprint del document publicat a: https://doi.org/10.1002/chem.200802597
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© Chemistry-A European Journal, 2009, vol. 15, núm. 14, p. 3359-3362
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Articles publicats (D-Q)
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Tots els drets reservats
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Company Casadevall, Anna Feng, Yan Güell Serra, Mireia Ribas Salamaña, Xavi Luis Luis, Josep Maria Que, Lawrence Costas Salgueiro, Miquel 2009 Olefin-Dependent Discrimination Between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations Chemistry-A European Journal 15 14 3359 3362
dc.title
Olefin-Dependent Discrimination Between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/acceptedVersion
dc.identifier.doi
dc.identifier.idgrec
010491
dc.contributor.funder
dc.type.peerreviewed
peer-reviewed
dc.identifier.eissn
1521-3765