Olefin-Dependent Discrimination Between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations

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orcId Company Casadevall, Anna​ researcherId Company Casadevall, Anna​ scopusId Company Casadevall, Anna​ ​
Company Casadevall, Anna
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Feng, Yan
​ ​ scopusId Güell Serra, Mireia​ ​
Güell Serra, Mireia
orcId Ribas Salamaña, Xavi​ ​ scopusId Ribas Salamaña, Xavi​ ​
Ribas Salamaña, Xavi
orcId Luis Luis, Josep Maria​ researcherId Luis Luis, Josep Maria​ scopusId Luis Luis, Josep Maria​ ​
Luis Luis, Josep Maria
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Que, Lawrence
orcId Costas Salgueiro, Miquel​ researcherId Costas Salgueiro, Miquel​ scopusId Costas Salgueiro, Miquel​ ​
Costas Salgueiro, Miquel
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Wet oxygenase models: Unprecedented high levels of water incorporation into products (up to 75 %) is observed in epoxidation reactions with H2O2 by a bioinspired nonheme iron catalyst. A surprising substrate‐dependent incorporation of water is observed, and is proposed to arise from fast equilibrium between two high‐valent HOFeVO isomeric species exhibiting different reactivity ​
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