Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex

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Dey, Raju
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Mohandas, Janet C.
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Samantaray, Manoja K.
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Hamieh, Ali
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Kavitake, Santosh
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Chen, Yin
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Abou-Hamad, Edy
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Cavallo, Luigi
orcId Poater Teixidor, Albert​ researcherId Poater Teixidor, Albert​ scopusId Poater Teixidor, Albert​ ​
Poater Teixidor, Albert
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Basset, Jean-Marie
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A novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl (TaMe5) has been described, by direct demethylation using B(C6F5)3 reagent. The aforesaid higher valent cationic tantalum complex was characterized precisely by liquid state 1H-NMR, 13C-NMR, and 1H-13C-NMR correlation spectroscopy ​
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