DUGiDocsSynthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex
dc.contributor.author
dc.date.accessioned
2018-11-28T08:08:03Z
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2018-11-28T08:08:03Z
dc.date.issued
2018-11-01
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dc.description.abstract
A novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl (TaMe5) has been described, by direct demethylation using B(C6F5)3 reagent. The aforesaid higher valent cationic tantalum complex was characterized precisely by liquid state 1H-NMR, 13C-NMR, and 1H-13C-NMR correlation spectroscopy
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This work was supported by funds from King Abdullah University of Science and Technology (KAUST) office of sponsored research (OSR). R.D. thanks National Institute of Technology, Calicut for financial support. A.P. thanks the Spanish MINECO for a project CTQ2014-59832-JIN
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application/pdf
dc.language.iso
eng
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MDPI (Multidisciplinary Digital Publishing Institute)
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info:eu-repo/grantAgreement/MINECO//CTQ2014-59832-JIN/ES/ESCANEO COMPUTACIONAL DE RELACIONES ESTRUCTURA%2FACTIVIDAD DE CATALIZADORES DE OXIDACION DEL AGUA PARA LA GENERACION DE H2/
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Reproducció digital del document publicat a: https://doi.org/10.3390/catal8110507
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Catalysts, 2018, vol. 8, núm. 11, p. 507
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Articles publicats (D-Q)
dc.rights
Attribution 4.0 International
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dc.subject
dc.title
Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex
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info:eu-repo/semantics/article
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info:eu-repo/semantics/openAccess
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info:eu-repo/semantics/publishedVersion
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dc.type.peerreviewed
peer-reviewed
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dc.identifier.eissn
2073-4344