DUGiDocsRegiospecific C-H bond activation: Reversible H/D exchange promoted by CuI complexes with triazamacrocyclic ligands
dc.contributor.author
dc.date.accessioned
2017-02-01T11:42:11Z
dc.date.available
2017-02-01T11:42:11Z
dc.date.issued
2006-04-28
dc.identifier.issn
1433-7851
dc.identifier.uri
dc.description
Aquest mateix article està publicat a l'edició alemanya d''Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2006, vol.118, núm. 18, p. 3007-3010. DOI http://dx.doi.org/10.1002/ange.200504222
dc.description.abstract
The first reversible and regiospecific H/D exchange promoted by CuI proceeds in weakly coordinating deuterated "acidic" solvents, such as [D6]acetone or [D 4]methanol (see scheme). The kinetics of the reaction have been studied in both directions (H/D and D/H exchange) by 1H and 2H NMR spectroscopy, and a molecular mechanism is proposed that is in accordance with all experimental and theoretical data
dc.description.sponsorship
This research was supported bythe MEC (Spain; projects BQU2003-02884, BQU2003-01677, and CTQ2005-08797-C02-01). X.R. is grateful for a Juan de la Cierva contract from MEC
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley
dc.relation
CICYT/PN 2000-2003/ BQU2000-0458
MEC/PN 2005-2008/CTQ2005-08797-C02-01
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.200504222
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© Angewandte Chemie - International Edition, 2006, vol. 45, núm. 18, p. 2941-2944
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Articles publicats (D-Q)
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Tots els drets reservats
dc.subject
dc.title
Regiospecific C-H bond activation: Reversible H/D exchange promoted by CuI complexes with triazamacrocyclic ligands
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
003892
dc.contributor.funder
dc.identifier.eissn
1521-3773