A novel carbene ruthenium complex as reusable and selective two-electron catalyst for alkene epoxidation

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Dakkach, Mohamed
​ ​ scopusId Fontrodona, Xavier​ ​
Fontrodona, Xavier
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Parella Coll, Teodor
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Atlamsani, Ahmed
orcId Romero García, Isabel​ researcherId Romero García, Isabel​ scopusId Romero García, Isabel​ ​
Romero García, Isabel
orcId Rodríguez Pizarro, Montserrat​ researcherId Rodríguez Pizarro, Montserrat​ ​ ​
Rodríguez Pizarro, Montserrat
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Novel-Carbene-Ruthenium.pdf embargoed access ​
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A new ruthenium aquo catalyst with the formula trans-[Ru(II)(CN-Me)(trpy) OH2](PF6)2 [where trpy=2,2a:6′,2″- terpyridine and CN-Me=3-methyl-1-(pyridin-2-yl)-imidazolylidene] has been prepared and thoroughly characterized by spectroscopic and electrochemical techniques. The complex has been tested in epoxidation catalysis both in dichloromethane and dichloromethane:ionic liquid media, displaying excellent performances and selectivities. Reuse of the catalyst in ionic liquid:solvent media has been explored for the first time in ruthenium-mediated epoxidation catalysis and its performance is fully maintained for up to ten runs ​
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