Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

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Manzini, Simone
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Cavallo, Luigi
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Nolan, Steven P.
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Urbina-Blanco, Cesar A.
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Nelson, David J.
orcId Poater Teixidor, Albert​ researcherId Poater Teixidor, Albert​ scopusId Poater Teixidor, Albert​ ​
Poater Teixidor, Albert
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Lebl, Tomas
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Meiries, Sébastien
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Slawin, Alexandra M. Z.
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Falivene, Laura
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The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored ​
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