DUGiDocsEvaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
dc.contributor.author
dc.date.accessioned
2016-11-30T12:05:29Z
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2016-11-30T12:05:29Z
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2015-03-15
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0022-328X
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dc.description.abstract
The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored
dc.description.sponsorship
SPN thanks the European Research Council (227817) (Advanced Investigator Award ‘FUNCAT’), the EU (CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ram on y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011- 293900)
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application/pdf
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eng
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Elsevier
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info:eu-repo/grantAgreement/MICINN//RYC-2009-05226/ES/RYC-2009-05226/
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Versió postprint del document publicat a: http://dx.doi.org/10.1016/j.jorganchem.2014.12.040
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© Journal of Organometallic Chemistry, 2015, vol. 780, p. 43-48
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Articles publicats (D-Q)
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Tots els drets reservats
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dc.title
Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
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info:eu-repo/semantics/article
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info:eu-repo/semantics/openAccess
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Cap
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info:eu-repo/grantAgreement/EC/FP7/293900/EU/Ab initio Statics and Molecular Dynamics Simulation of Olefin Metathesis Catalysts for pharmacological purposes/COMPUTEDRUG
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info:eu-repo/semantics/acceptedVersion
peer-reviewed
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