{ "dc.contributor.author": "Broggi, Julie" , "dc.contributor.author": "Jurcik, Vaclav" , "dc.contributor.author": "Songis, Olivier" , "dc.contributor.author": "Poater Teixidor, Albert" , "dc.contributor.author": "Cavallo, Luigi" , "dc.contributor.author": "Slawin, Alexandra M. Z." , "dc.contributor.author": "Cazin, Catherine S. J." , "dc.date.accessioned": "2013-12-03T12:42:40Z" , "dc.date.available": "2013-12-03T12:42:40Z" , "dc.date.issued": "2013" , "dc.identifier.issn": "0002-7863" , "dc.identifier.uri": "http://hdl.handle.net/10256/8652" , "dc.description.abstract": "The [Pd(SIPr)(PCy3)] complex efficiently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C-C multiple bonds using H-2 formed in situ. The isolation of a key catalytic hydridoformatopalladium species, [Pd{OC(O)H}(H)(IPr)(PCy3)], is reported. The complex plays a key role in the Pd(0)-mediated formation of hydrogen from formic acid. Mechanistic and computational studies delineate the operational role of the palladium complex in this efficient tandem sequence" , "dc.description.sponsorship": "The EPSRC and the Royal Society (University Research Fellowship to C.S.J.C.), the Spanish MICINN (Ramon y Cajal Contract RYC-2009-05226 to A.P.), the EC (Career Integration Grant CIG09-GA-2011-293900 to A.P.), and Generalitat de Catalunya (BE Fellowship 2011BE100793 to A.P.) are acknowledged for financial support" , "dc.format.mimetype": "application/pdf" , "dc.language.iso": "eng" , "dc.publisher": "American Chemical Society" , "dc.relation": "info:eu-repo/grantAgreement/MICINN//RYC-2009-05226/ES/RYC-2009-05226/" , "dc.relation": "AGAUR/2011BE100793" , "dc.relation.isformatof": "Reproducció digital del document publicat a: http://dx.doi.org/10.1021/ja311087c" , "dc.relation.ispartof": "© Journal of the American Chemical Society, 2013, vol. 135, núm. 12, p. 4588-4591" , "dc.relation.ispartofseries": "Articles publicats (D-Q)" , "dc.rights": "Tots els drets reservats" , "dc.subject": "Compostos heterocíclics" , "dc.subject": "Heterocyclic compounds" , "dc.subject": "Catàlisi" , "dc.subject": "Catalysis" , "dc.title": "The Isolation of [Pd{OC(O)H}(H)(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid" , "dc.type": "info:eu-repo/semantics/article" , "dc.rights.accessRights": "info:eu-repo/semantics/embargoedAccess" , "dc.embargo.terms": "Cap" , "dc.relation.projectID": "info:eu-repo/grantAgreement/EC/FP7/293900/EU/Ab initio Statics and Molecular Dynamics Simulation of Olefin Metathesis Catalysts for pharmacological purposes/COMPUTEDRUG" , "dc.type.version": "info:eu-repo/semantics/publishedVersion" , "dc.identifier.doi": "http://dx.doi.org/10.1021/ja311087c" , "dc.contributor.funder": "Ministerio de Ciencia e Innovación (Espanya)" , "dc.contributor.funder": "Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca" , "dc.relation.FundingProgramme": "FP7" , "dc.relation.ProjectAcronym": "COMPUTEDRUG" , "dc.identifier.eissn": "1520-5126" }