{ "dc.contributor.author": "Chu, Terry" , "dc.contributor.author": "Vyboishchikov, Sergei F." , "dc.contributor.author": "Gabidullin, Bulat" , "dc.contributor.author": "Nikonov, Georgii I." , "dc.date.accessioned": "2017-02-15T07:15:09Z" , "dc.date.available": "2017-02-15T07:15:09Z" , "dc.date.issued": "2016-10-10" , "dc.identifier.issn": "1433-7851 (versió paper)" , "dc.identifier.issn": "1521-3773 (versió electrònica)" , "dc.identifier.uri": "http://hdl.handle.net/10256/13589" , "dc.description": "Aquest mateix article està publicat a l'edició alemanya d''Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2016, vol.128, núm. 42, p. 13500–13505. DOI http://dx.doi.org/10.1002/ange.201607735" , "dc.description.abstract": "The treatment of cyclic thioureas with the aluminum(I) compound NacNacAl (1; NacNac=[ArNC(Me)CHC(Me)NAr]−, Ar=2,6-Pri2C6H3) resulted in oxidative cleavage of the C=S bond and the formation of 3 and 5, the first monomeric aluminum complexes with an Al=S double bond stabilized by N-heterocyclic carbenes. Compound 1 also reacted with triphenylphosphine sulfide in a similar manner, which resulted in cleavage of the P=S bond and production of the adduct [NacNacAl=S(S=PPh3)] (8). The Al=S double bond in 3 can react with phenyl isothiocyanate to furnish the cycloaddition product 9 and zwitterion 10 as a result of coupling between the liberated carbene and PhN=C=S. All novel complexes were characterized by multinuclear NMR spectroscopy, and the structures of 5, 9, and 10 were confirmed by X-ray diffraction analysis. The nature of the Al=S bond in 5 was also probed by DFT calculation" , "dc.description.sponsorship": "Financial support from the Spanish Ministerio de Economía y Competitividad in the form of grant CTQ2014-54306-P to S.F.V. is appreciated" , "dc.format.mimetype": "application/pdf" , "dc.language.iso": "eng" , "dc.publisher": "Wiley" , "dc.relation": "MINECO/PE 2015-2017/CTQ2014-54306-P" , "dc.relation.isformatof": "Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.201607735" , "dc.relation.ispartof": "© Angewandte Chemie International Edition, 2016, vol. 55, núm. 42, p. 13306-13311" , "dc.relation.ispartofseries": "Articles publicats (D-Q)" , "dc.rights": "Tots els drets reservats" , "dc.subject": "C=S activation" , "dc.subject": "N-heterocyclic carbenes" , "dc.subject": "oxidative addition" , "dc.subject": "Sulfat d'alumini" , "dc.subject": "Aluminum sulfate" , "dc.subject": "Funcional de densitat, Teoria del" , "dc.subject": "Density functionals" , "dc.title": "Oxidative Cleavage of C=S and P=S Bonds at an AlI Center: Preparation of Terminally Bound Aluminum Sulfides" , "dc.type": "info:eu-repo/semantics/article" , "dc.rights.accessRights": "info:eu-repo/semantics/embargoedAccess" , "dc.embargo.terms": "Cap" , "dc.type.version": "info:eu-repo/semantics/publishedVersion" , "dc.identifier.doi": "http://dx.doi.org/10.1002/anie.201607735" , "dc.identifier.idgrec": "025926" , "dc.contributor.funder": "Ministerio de Economía y Competitividad (Espanya)" }