{ "dc.contributor.author": "Farjas Silva, Jordi" , "dc.contributor.author": "Camps, Johan" , "dc.contributor.author": "Roura Grabulosa, Pere" , "dc.contributor.author": "Ricart, Susagna" , "dc.contributor.author": "Puig Molina, Teresa" , "dc.contributor.author": "Obradors, Xavier" , "dc.date.accessioned": "2015-10-27T12:31:15Z" , "dc.date.available": "2015-10-27T12:31:15Z" , "dc.date.issued": "2012-09-20" , "dc.identifier.issn": "0040-6031" , "dc.identifier.uri": "http://hdl.handle.net/10256/11387" , "dc.description.abstract": "A detailed analysis of the thermal decomposition of barium trifluoroacetate under different atmospheres is presented. Thermogravimetry, differential thermal analysis, and evolved gas analysis have been used for this in situ analysis. The presence of oxygen significantly advances the decomposition, while the presence of water vapor has a minor effect. The process is exothermic, the heat evolved being significantly larger in the presence of oxygen. The final product is BaF 2, which is stable up to 1200 °C. The underlying mechanism has been disclosed thanks to MS analysis of the volatiles formed during decomposition" , "dc.description.sponsorship": "This work was partially funded by the Spanish Programa National de Materiales through projects MAT2011-28874-C02-01 and MAT2011-28874-C02-02, by the Consolider program Nanoselect, CSD2007-00041, EU project NESPA-RTN and by the Generalitat de Catalunya contracts Nos. 2009SGR-185 and 2009SGR-770" , "dc.format.mimetype": "application/pdf" , "dc.language.iso": "eng" , "dc.publisher": "Elsevier" , "dc.relation": "MICINN/PN 2012-2014/MAT2011-28874-C02-02" , "dc.relation": "AGAUR/2009-2013/2009 SGR-185" , "dc.relation.isformatof": "Reproducció digital del document publicat a: http://dx.doi.org/10.1016/j.tca.2012.06.020" , "dc.relation.ispartof": "© Thermochimica Acta, 2012, vol. 544, p. 77-83" , "dc.relation.ispartofseries": "Articles publicats (D-F)" , "dc.rights": "Tots els drets reservats" , "dc.subject": "Anàlisi tèrmica" , "dc.subject": "Thermal analysis" , "dc.subject": "Compostos de bari" , "dc.subject": "Barium compounds" , "dc.title": "The thermal decomposition of barium trifluoroacetate" , "dc.type": "info:eu-repo/semantics/article" , "dc.rights.accessRights": "info:eu-repo/semantics/embargoedAccess" , "dc.embargo.terms": "Cap" , "dc.type.version": "info:eu-repo/semantics/publishedVersion" , "dc.identifier.doi": "http://dx.doi.org/10.1016/j.tca.2012.06.020" , "dc.contributor.funder": "Ministerio de Ciencia e Innovación (Espanya)" , "dc.contributor.funder": "Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca" }