Thermal decomposition of barium trifluoroacetate thin films

dc.contributor.author
Eloussifi, Hichem
Farjas Silva, Jordi
Roura Grabulosa, Pere
Ricart, Susagna
Puig Molina, Teresa
Obradors, Xavier
Dammak, Mohamed
dc.date.accessioned
2015-01-13T09:20:51Z
dc.date.available
2017-01-13T04:00:05Z
dc.date.issued
2013
dc.identifier.issn
0040-6031
dc.identifier.uri
http://hdl.handle.net/10256/9833
dc.description.abstract
The thermal decomposition of barium trifluoroacetate thin films under different atmospheres is presented. Thermogravimetry and evolved gas analysis have been used for this in situ analysis. We focus our attention on the different behavior exhibited by films when compared to powders. The decomposition of barium trifluoroacetate is altered due to the faster out-diffusion of the product reaction:CF2. After barium trifluoroacetate decomposition a stable intermediate, barium fluoride, is formed. The decomposition of barium fluoride is diffusion controlled and depends on water partial pressure
dc.description.sponsorship
This work was partially funded by the Spanish Programa Nacional de Materiales through projects MAT2011-28874-C02-01 and MAT2011-28874-C02-02, by the Consolider program Nanoselect, CSD2007-00041, EU project NESPA-RTN and by the Generalitat de Catalunya contracts No. 2009SGR-185 and 2009SGR-770
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
dc.relation
info:eu-repo/grantAgreement/MICINN//MAT2011-28874-C02-02/ES/NANOESTRUCTURAS TENSIONADAS PARA CINTAS SUPERCONDUCTORAS DE YBCO DE BAJO COSTE Y PRESTACIONES ELEVADAS.: ANALISIS TERMICO AVANZADO/
AGAUR/2009-2013/2009 SGR-185
dc.relation.isformatof
Versió postprint del document publicat a: http://dx.doi.org/10.1016/j.tca.2013.01.022
dc.relation.ispartof
© Thermochimica Acta, 2013, vol. 556, p. 58-62
dc.relation.ispartofseries
Articles publicats (D-F)
dc.rights
Tots els drets reservats
dc.subject
Mass spectrometry
Thin films
Espectrometria de masses
Compostos de bari
Barium compounds
Capes fines
Anàlisi tèrmica
Thermal analysis
Capes fines de compostos de bari
Thin films barium compounds
dc.title
Thermal decomposition of barium trifluoroacetate thin films
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/acceptedVersion
dc.identifier.doi
http://dx.doi.org/10.1016/j.tca.2013.01.022
dc.identifier.idgrec
017611
dc.contributor.funder
Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca
dc.relation.ProjectAcronym
NANOESTRUCTURAS TENSIONADAS PARA CINTAS SUPERCONDUCTORAS DE YBCO DE BAJO COSTE Y PRESTACIONES ELEVADAS.: ANALISIS TERMICO AVANZADO
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