Exact analytical solution for the Kissinger equation: Determination of the peak temperature and general properties of thermally activated transformations
dc.contributor.author
dc.date.accessioned
2014-11-26T10:25:34Z
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2016-12-21T04:01:33Z
dc.date.issued
2014
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0040-6031
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dc.description.abstract
A key parameter of many transformations when heated at a constant rate is the peak temperature, i.e., the temperature at which the transformation rate is at its maximum. The most universal approach to determine the peak temperature for thermally activated transformations is the Kissinger equation. In this paper, we solve Kissinger equation to deduce the exact dependence of the peak temperature on the heating rate. This analytical solution is based on the Lambert W-function. In addition, an approximate solution is derived that is used to infer general properties of thermally activated processes and to obtain a test to check the validity of Kissinger method
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This work was partially funded by the Spanish Programa Nacional de Materiales through project MAT2011-28874-C02-02 and by the Generalitat de Catalunya contract No. 2009SGR-185
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8 p.
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application/pdf
dc.language.iso
eng
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Elsevier
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info:eu-repo/grantAgreement/MICINN//MAT2011-28874-C02-02/ES/NANOESTRUCTURAS TENSIONADAS PARA CINTAS SUPERCONDUCTORAS DE YBCO DE BAJO COSTE Y PRESTACIONES ELEVADAS.: ANALISIS TERMICO AVANZADO/
AGAUR/2009-2013/2009 SGR-185
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Versió postprint del document publicat a: http://dx.doi.org/10.1016/j.tca.2014.10.024
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© Thermochimica Acta, 2014, vol. 598, p. 51-58
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Articles publicats (D-F)
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Tots els drets reservats
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Farjas Silva, Jordi Roura Grabulosa, Pere 2014 Exact analytical solution for the Kissinger equation: Determination of the peak temperature and general properties of thermally activated transformations Thermochimica Acta 598 51 58
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dc.title
Exact analytical solution for the Kissinger equation: Determination of the peak temperature and general properties of thermally activated transformations
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info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
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info:eu-repo/semantics/acceptedVersion
dc.identifier.doi
dc.identifier.idgrec
022272
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