Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese (IV) Oxo Complex

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orcId Garcia Bosch, Isaac​ ​ scopusId Garcia Bosch, Isaac​ ​
Garcia Bosch, Isaac
orcId Company Casadevall, Anna​ researcherId Company Casadevall, Anna​ scopusId Company Casadevall, Anna​ ​
Company Casadevall, Anna
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Cady, Clyde W.
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Styring, Stenbjörn
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Browne, Wesley R.
orcId Ribas Salamaña, Xavi​ ​ scopusId Ribas Salamaña, Xavi​ ​
Ribas Salamaña, Xavi
orcId Costas Salgueiro, Miquel​ researcherId Costas Salgueiro, Miquel​ scopusId Costas Salgueiro, Miquel​ ​
Costas Salgueiro, Miquel
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HAT trick: [MnIV(OH)2(H,MePytacn)]2+ (A) and [MnIV(O)(OH)(H,MePytacn)]+ (B) differ in their reactions with CH bonds: compound A engages in typical single-step hydrogen atom transfer (HAT) reactions, whereas B first forms a substrate–B encounter complex (C; see scheme). This equilibrium alters the relative CH reactivity from that expected from CH bond dissociation energies ​
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