DUGiDocsMultitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
dc.contributor.author
dc.date.accessioned
2025-01-13T18:15:48Z
dc.date.available
2025-01-13T18:15:48Z
dc.date.issued
2025-01-10
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1523-7060
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dc.description.abstract
A method to synthesize coplanar dimeric porphyrins bearing eight corannulene units has been developed. It relies on the stability of octahedral CO-capped Ru(II) complexes linked by N-donor ligands. This specific arrangement provides an optimal scaffold to accommodate fullerenes by imposing corannulene groups at precise distance and relative orientation. Their capabilities for C60 recognition have been thoroughly assessed, revealing that each system can encapsulate up to four buckyballs, giving rise to a compact supramolecular complex echoing a discrete donor-acceptor-donor trilayer offer-ing significant potential properties for further exploitation
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The authors thank the SpanishMinistry of Science and Innovation (MCIN) (PID2021-124691NB-I00, funded by MCIN/AEI/10.13039/501100011033/FEDER,UE) for funding. N.A.-L. acknowledges the University of Valladolid and Santander Bank for apredoctoral contract.A.D.-V. acknowledges the Ministerio de Universidades and the European Union-Next Generation EU for the María Zambrano contract (ADV ,CONVREC-2021-264). M.S. is grateful for financial support from the Spanish Ministry of Science and Innovation (MCIN/AEI/10.13039/501100011033; Network RED202214939-T, Project PID2023-147424NB-I00) and the Catalan Conselleria de Recerca i Universitats of the Generalitat de Catalunya (Project 2021SGR623). A.J.S. is grateful for financial support from the Spanish Ministry of Science and Innovation (AEI/10.13039/501100011033, Grant CEX 2021001202-M) and also gratefully acknowledges Poland’s highperformance computing infrastructure PLGrid (HPC Centers: ACK Cyfronet AGH) for providing computer facilities and support within Computational Grants PLG/2023/016841
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6 p.
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application/pdf
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eng
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American Chemical Society (ACS)
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PID2023-147424NB-I00
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Reproducció digital del document publicat a: https://doi.org/10.1021/acs.orglett.4c04385
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Organic Letters, 2025, vol. 27, núm. 1, p. 357-362
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Articles publicats (D-Q)
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Reconeixement 4.0 Internacional
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dc.source
Álvarez-Llorente, Nerea Stasyuk, Anton J. Diez-Varga, Alberto Solà i Puig, Miquel Barbero, Héctor Álvarez, Celedonio M. 2025 Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles Organic Letters 27 1 357 362
dc.title
Multitopic Corannulene-Porphyrin Hosts for Fullerenes: A Three-Layer Scaffold for Precisely Designed Supramolecular Ensembles
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147424NB-I00/ES/DISEÑO COMPUTACIONAL DE COMPUESTOS ORGANICOS PICONJUGADOS PARA APLICACIONES FOTOVOLTAICAS Y OPTOELECTRONICAS/
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
039610
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dc.identifier.eissn
1523-7052
dc.identifier.PMID
39705117