DUGiDocsThe cycloaddition chemistry of 3-oxidopyraziniums. Dimerisation of 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium
dc.contributor.author
dc.date.accessioned
2024-07-29T06:27:15Z
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2024-07-29T06:27:15Z
dc.date.issued
2024-06-12
dc.identifier.issn
1551-7004
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dc.description.abstract
3-Oxidopyraziniums are accessed from 2(1H)-pyrazinones via N-alkylation and then exposure of the resulting pyrazinium salts to mild base at room temperature. 3-Oxidopyraziniums react with acrylates in a 1,3-dipolar cyclisation producing 3,8-diazabicyclo[3.2.1]octanes. 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium (C14H16N2O2) dimerises at room temperature, forming a tetracyclic alcohol C28H34N4O5, the structure of which was elucidated using spectroscopic and X-ray analyses
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application/pdf
dc.language.iso
eng
dc.publisher
ARKAT USA, Inc.
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Reproducció digital del document publicat a: https://doi.org/10.24820/ark.5550190.p012.217
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ARKIVOC: free online journal of organic chemistry, 2024, vol. 1, art. núm. 202412217
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Articles publicats (D-Q)
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Reconeixement 4.0 Internacional
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dc.source
Riesco-Llach, Gerard Planas i Grabuleda, Marta Feliu Soley, Lídia Joule, John A. 2024 The cycloaddition chemistry of 3-oxidopyraziniums. Dimerisation of 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium ARKIVOC : free online journal of organic chemistry 1 art.nú202412217
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dc.title
The cycloaddition chemistry of 3-oxidopyraziniums. Dimerisation of 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium
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info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
039041
dc.identifier.eissn
1551-7012