DUGiDocsGeneration of Ru(iii)-hypochlorite with resemblance to the heme-dependent haloperoxidase enzyme
dc.contributor.author
dc.date.accessioned
2023-10-26T11:40:53Z
dc.date.available
2023-10-26T11:40:53Z
dc.date.issued
2023-08-09
dc.identifier.issn
1477-9226
dc.identifier.uri
dc.description.abstract
The reaction of [(Me/BnTPEN)RuII(NCCH3)]2+ (BnTPEN = N1-benzyl-N1,N2,N2-tris(pyridine-2-ylmethyl)ethane-1,2-diamine and MeTPEN = N1-methyl-N1,N2,N2-tris(pyridine-2-ylmethyl)ethane-1,2-diamine) with mCPBA in the presence of chloride ions in CH3CN : H2O generated a novel (Me/BnTPEN)RuIII-OCl species at room temperature. This hypochlorite adduct could also be obtained by the direct reaction of NaOCl and HClO4 with (L)RuII complexes. The current study mimics the synthesis of a metal hypochlorite adduct in a similar fashion as in the heme-dependent haloperoxidase enzyme. As an electrophilic oxidant, the ruthenium hypochlorite adduct catalyzes hydrogen atom abstraction reactions of phenols and their derivatives
dc.description.sponsorship
The work presented here is financially supported by SERB (CRG/2019/003058), CSIR (01(3050)/21/EMR-II), AEI/MCIN (PID2020-114548GB-I00), and GenCat (2021 SGR 00487, 2022 FI_B 00118). Software for Chemistry & Materials (SCM) is acknowledged for a generous developer's license to MS. RK and AA are grateful to IIT Kanpur for their institute fellowships.
Open Access funding provided thanks to the CSUC agreement with Royal Society of Chemistry (RSC)
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.relation.isformatof
Reproducció digital del document publicat a: https://doi.org/10.1039/D3DT02028B
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Dalton Transactions, 2023, vol. 52, p. 12552-12559
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Articles publicats (D-Q)
dc.rights
Attribution 4.0 International
dc.rights.uri
dc.subject
dc.title
Generation of Ru(iii)-hypochlorite with resemblance to the heme-dependent haloperoxidase enzyme
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
037243
dc.type.peerreviewed
peer-reviewed
dc.identifier.eissn
1477-9234