Carbon Dioxide Conversion on Supported Metal Nanoparticles: A Brief Review
dc.contributor.author
dc.date.accessioned
2023-02-03T11:14:28Z
dc.date.available
2023-02-03T11:14:28Z
dc.date.issued
2023-01-30
dc.identifier.uri
dc.description.abstract
The increasing concentration of anthropogenic CO2 in the air is one of the main causes of global warming. The Paris Agreement at COP 21 aims to reach the global peak of greenhouse gas emissions in the second half of this century, with CO2 conversion towards valuable added compounds being one of the main strategies, especially in the field of heterogeneous catalysis. In the current search for new catalysts, the deposition of metallic nanoparticles (NPs) supported on metal oxides and metal carbide surfaces paves the way to new catalytic solutions. This review provides a comprehensive description and analysis of the relevant literature on the utilization of metal-supported NPs as catalysts for CO2 conversion to useful chemicals and propose that the next catalysts generation can be led by single-metal-atom deposition, since in general, small metal particles enhance the catalytic activity. Among the range of potential indicators of catalytic activity and selectivity, the relevance of NPs’ size, the strong metal–support interactions, and the formation of vacancies on the support are exhaustively discussed from experimental and computational perspective
dc.description.sponsorship
This research was funded by the Spanish Ministerio de Ciencia e Innovación (projects PID2021-127423NB-I00 to A.P. and PID2020-113711GB-I00 to M.S.) and the Generalitat de Catalunya (project 2021 SGR0623 and ICREA Academia prize 2019 to A.P.). S.P.-P. appreciates the economic support of the Marie Curie fellowship (H2020-MSCA-IF-2020-101020330)
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
MDPI (Multidisciplinary Digital Publishing Institute)
dc.relation
PID2021-127423NB-I00
PID2020-113711GB-I00
dc.relation.isformatof
Reproducció digital del document publicat a: https://doi.org/10.3390/catal13020305
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Catalysts, 2023, vol. 13, núm. 2, p. 305
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Articles publicats (D-Q)
dc.rights
Attribution 4.0 International
dc.rights.uri
dc.subject
dc.title
Carbon Dioxide Conversion on Supported Metal Nanoparticles: A Brief Review
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.relation.projectID
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113711GB-I00/ES/DISEÑO Y SINTESIS DE FULLERENOS PARA LA CONSTRUCCION DE CELDAS SOLARES HIBRIDAS DE PEROVSKITA Y FULERENOS D ALTO RENDIMIENTO. UN ENFOQUE EXPERIMENTAL Y COMPUTACIONAL SINERGICO/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-127423NB-I00/ES/CATÀLISIS PREDICTIVA PARA CAMBIAR EL ORDEN SECUENCIAL ENTRE EXPERIMENTOS I CÁLCULOS/
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
036695
dc.contributor.funder
dc.type.peerreviewed
peer-reviewed
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
2073-4344
dc.description.ods
13. Acción por el clima