Aromaticity and Extrusion of Benzenoids Linked to [o -COSAN]−: Clar Has the Answer

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orcId Poater i Teixidor, Jordi​ researcherId Poater i Teixidor, Jordi​ scopusId Poater i Teixidor, Jordi​ ​
Poater i Teixidor, Jordi
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Viñas, Clara
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Olid, David
orcId Solà i Puig, Miquel​ researcherId Solà i Puig, Miquel​ scopusId Solà i Puig, Miquel​ ​
Solà i Puig, Miquel
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Teixidor Bombardó, Francesc
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AngewandteChemieIntEdition-Aromaticity.pdf 751.8  Kb | PDF AngewandteChemie-Aromaticity.pdf 748.9  Kb | PDF ​
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Benzene and pyrene can be synthetically linked to [o-COSAN]- keeping their aromaticity. At difference, naphthalene and anthracene are extruded in the same reaction. We have proven that extrusion is only favorable if the number of Clar's π-sextets remains constant. Thus, Clar has the answer to whether an attached polycyclic aromatic hydrocarbon to [o-COSAN]- is extruded or not ​
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