DUGiDocsNickel-catalyzed Csp2-OMe functionalization for chemoselective aromatic homologation en route to nanographenes
dc.contributor.author
dc.date.accessioned
2022-04-08T10:12:49Z
dc.date.available
2022-04-08T10:12:49Z
dc.date.issued
2022-03-24
dc.identifier.issn
0947-6539
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dc.description.abstract
A Ni-catalyzed Csp2−OMe ortho-functionalization methodology to form chemoselectively alkyne monoannulation or aromatic homologation products is reported as a novel protocol towards the valorisation of substrates containing Csp2−OMe units. Double activation of Csp2−OMe and Csp2−F bonds is also demonstrated. Further use of aromatic homologation products towards the synthesis of nanographene-like compounds is described
dc.description.sponsorship
This work was financially supported by grants from MINECO Spain (CTQ2016-77989-P and PID2019-104498GB-I00 to
X.R.), the DFG (Gottfried-Wilhelm-Leibniz award to L.A.),
and Generalitat de Catalunya (2017SGR264 and ICREA
Acadèmia to X.R.)
Open Access funding provided thanks to the CRUE-CSIC agreement with Wiley
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley
dc.relation
MINECO/PE 2016-2018/CTQ2016-77989-P
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Reproducció digital del document publicat a: https://doi.org/10.1002/chem.202200625
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Chemistry-A European Journal, 2022, vol. Online Version of Record before inclusion in an issue, art.núm. e202200625
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Articles publicats (D-Q)
dc.rights
Reconeixement-NoComercial-SenseObraDerivada 4.0 Internacional
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dc.source
Capdevila Güell, Lorena Sala, Judith Ackermann, Lutz Ribas Salamaña, Xavi 2022 Nickel-catalyzed Csp2-OMe functionalization for chemoselective aromatic homologation en route to nanographenes Chemistry-A European Journal Online Version e202200625
dc.subject
dc.title
Nickel-catalyzed Csp2-OMe functionalization for chemoselective aromatic homologation en route to nanographenes
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.relation.projectID
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104498GB-I00/ES/NANOCAPSULAS COMO PLATAFORMAS SUPRAMOLECULARES PARA LA FUNCIONALIZACION REGIOSELECTIVA DE FULLERENOS Y CATALISIS EN EL ESPACIO CONFINADO/
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
035212
dc.contributor.funder
dc.type.peerreviewed
peer-reviewed
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dc.identifier.eissn
1521-3765