DUGiDocsOrganometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
dc.contributor.author
dc.date.accessioned
2022-04-08T09:49:07Z
dc.date.available
2023-05-23T09:50:07Z
dc.date.issued
2022-01-13
dc.identifier.issn
2052-1553
dc.identifier.uri
dc.description.abstract
Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(II) and Ni(III) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni(IV) organometallic complex, and its relevance to C-C and C-O bond formation reactivity studies is discussed
We acknowledge financial support from NSF CHE-1925751 to
L.M., MINECO-Spain for projects PID2019-104498GB-I00 to
X.R., PID2019-106699GB-I00 to A.C. Generalitat de
Catalunya is also acknowledged for project 2017SGR264
dc.format.extent
7 p.
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.relation.isformatof
Versió postprint del document publicat a: https://doi.org/10.1039/d1qi01486b
dc.relation.ispartof
© Inorganic Chemistry Frontiers, 2022, vol. 9, num. 5, p. 1016-1022
dc.relation.ispartofseries
Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.source
Magallón, Carla Griego, Leonel Hu, C. H. Company Casadevall, Anna Ribas Salamaña, Xavi Mirica, Liviu M. 2022 Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions Inorganic Chemistry Frontiers 9 5 1016 1022
dc.subject
dc.title
Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.embargo.terms
2023-01-13T00:00:00Z
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2023-01-13
dc.relation.projectID
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-095458-B-I00/ES/POLITEIA BIBLICA Y RELIGION CIVICA EN LA MONARQUIA CATOLICA (SIGLOS XVI-XIX). DISCURSOS, PRACTICAS, CONTRASTES/
dc.type.version
info:eu-repo/semantics/acceptedVersion
dc.identifier.doi
dc.identifier.idgrec
035211
dc.contributor.funder
dc.type.peerreviewed
peer-reviewed
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
2052-1553