Hydrogenation of α,β‐unsaturated carbonyl compounds over covalently heterogenized Ru(II) diphosphine complexes on AlPO4‐sepiolite supports
dc.contributor.author
dc.date.accessioned
2021-03-23T10:11:09Z
dc.date.available
2021-03-23T10:11:09Z
dc.date.issued
2021-02-22
dc.identifier.uri
dc.description.abstract
In this work, the covalent immobilization of two ruthenium(II) complexes, i.e., [RuIICl (bpea){(S)(‐)(BINAP)}](BF4), 1, and [RuIICl(bpea)(DPPE)](BF4), 2, where BINAP = 2,2'‐bis(diphenylphosphino)‐ 1,1'‐binaphthyl and DPPE = 1,2‐bis(diphenylphosphino)ethane, have been obtained (AlPO4‐Sepiolite@1 and AlPO4‐Sepiolite@2) by using a N‐tridentate ligand N,N‐bis‐(2‐pyridylmethyl) ethylamine (bpea), linked to an amorphous AlPO4‐Sepiolite (20/80) inorganic support. This AlPO4‐sepiolite support is able to immobilize the double amount of ruthenium complex (1.65%) than the amorphous AlPO4 (0.89%). Both heterogenized complexes have been assessed as catalysts in the liquid phase hydrogenation of several substrates with carbonyl and/or olefinic double bonds using methanol as solvent, attaining good catalytic activity and high enantioselectivity (99%). The highest Turn Over Number (TON) value (748.6) was obtained over the [RuII Cl (bpea)(DPPE)](BF4) 2 catalyst, although the [RuIICl(bpea){(S)(‐)(BINAP)}](BF4) 1 exhibits better reusability. In fact, the [RuIICl(bpea){(S)(‐)(BINAP)}](BF4) immobilized on AlPO4‐Sepiolite maintained the activity throughout 14 successive runs. Furthermore, some findings on hydrogenation mechanisms of the α,β‐unsaturated carbonyl compounds over Ru catalysts have been also obtained
dc.description.sponsorship
The authors are thankful to MINECO‐ENE2016‐81013‐R (AEI/FEDER, EU),
MICIIN (Project ref. PID2019‐104953RB‐100), Consejería de Transformación Económica, Industria, Conocimiento y Universidades de la Junta de Andalucía (UCO‐FEDER Project CATOLIVAL, ref.
1264113‐R, 2018 call and Project ref. P18‐RT‐4822) and FEDER Funds for financial support
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
MDPI (Multidisciplinary Digital Publishing Institute)
dc.relation.isformatof
Reproducció digital del document publicat a: https://doi.org/10.3390/catal11020289
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Catalysts, 2021, vol. 11, núm. 2, p. 289
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Articles publicats (D-Q)
dc.rights
Reconeixement 4.0 Internacional
dc.rights.uri
dc.source
Caballero, Verónica Estevez, Rafael Luna, Diego Bautista, Felipa M. Romero, Antonio A. Aguado-Deblas, Laura Hidalgo-Carrillo, Jesús Romero García, Isabel 2021 Hydrogenation of α,β‐unsaturated carbonyl compounds over covalently heterogenized Ru(II) diphosphine complexes on AlPO4‐sepiolite supports Catalysts 11 2 289
dc.subject
dc.title
Hydrogenation of α,β‐unsaturated carbonyl compounds over covalently heterogenized Ru(II) diphosphine complexes on AlPO4‐sepiolite supports
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
033208
dc.type.peerreviewed
peer-reviewed
dc.identifier.eissn
2073-4344