DUGiDocsO-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core
dc.contributor.author
dc.date.accessioned
2019-05-07T08:31:48Z
dc.date.available
2019-05-07T08:31:48Z
dc.date.issued
2012-03-05
dc.identifier.issn
0947-6539
dc.identifier.uri
dc.description.abstract
The FeIIcomplex of a hexanuclear non-heme ligand performs an OO bond formation reaction using iodosobenzene as the oxygen source. On the basis of infrared, UV/Vis, kinetic and DFT studies a radical coupled OO bond formation mechanism is proposed (see scheme). These findings are extremely important for the design and discovery of faster and cheaper water oxidation catalysts
dc.description.sponsorship
We gratefully acknowledge financial support of this work from the Cluster of
Excellence “Unifying Concepts in Catalysis” (EXC 314/1), Marie Curie Fellowships (PIEF-GA-2008-221734 and 236013), the Polish Ministry of Science (N N 204 215634), the Generalitat de Catalunya (2009SGR528) and MEC-Spain (CTQ2008-06696/BQU )
dc.format.extent
5 p.
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley
dc.relation
info:eu-repo/grantAgreement/MICINN//CTQ2008-06696/ES/MODELIZACION QUIMICO-CUANTICA MEJORADA DE PROCESOS EN EL ESTADO EXCITADO: EFECTOS DE ENTORNO Y SUPERFICIES PARA EL CONTROL COHERENTE/
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Versió postprint del document publicat a: https://doi.org/10.1002/chem.201102326
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© Chemistry-A European Journal, 2012, vol. 18, núm. 10, p. 2787-2791
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Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.source
Kundu, Subrata Matito i Gras, Eduard Walleck, Stephan Pfaff, Florian F. Heims, Florian Rábay, Battist Luis Luis, Josep Maria Company Casadevall, Anna Braun, Beatrice Glaser, Thorsten Ray, Kallol 2012 O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core Chemistry-A European Journal 18 10 2787 2791
dc.subject
dc.title
O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/acceptedVersion
dc.identifier.doi
dc.identifier.idgrec
016078
dc.contributor.funder
dc.type.peerreviewed
peer-reviewed
dc.relation.ProjectAcronym
dc.identifier.eissn
1521-3765