An Alternative Reaction Pathway for Iridium-Catalyzed Water Oxidation Driven by Cerium Ammonium Nitrate (CAN)
dc.contributor.author
dc.date.accessioned
2018-12-17T08:39:18Z
dc.date.available
2018-12-17T08:39:18Z
dc.date.issued
2016-06-10
dc.identifier.issn
2155-5435
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dc.description.abstract
The generation of solar fuels by means of a photosynthetic apparatus strongly relies on the development of an efficient water oxidation catalyst (WOC). Cerium ammonium nitrate (CAN) is the most commonly used sacrificial oxidant to explore the potentiality of WOCs. It is usually assumed that CAN has the unique role to oxidatively energize WOCs, making them capable to offer a low-energy reaction pathway to transform H2O to O2. Herein, we show that CAN might have a much more relevant and direct role in WO, mainly related to the capture and liberation of O-O-containing molecular moieties
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application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
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Reproducció digital del document publicat a: https://doi.org/10.1021/acscatal.6b01325
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© ACS Catalysis, 2016, vol. 6, núm. 7, p. 4559-4563
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Articles publicats (D-Q)
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Tots els drets reservats. This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes
dc.subject
dc.title
An Alternative Reaction Pathway for Iridium-Catalyzed Water Oxidation Driven by Cerium Ammonium Nitrate (CAN)
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
025569
dc.type.peerreviewed
peer-reviewed