The critical condition for thermal explosion in an isoperibolic system
dc.contributor.author
dc.date.accessioned
2017-09-15T10:08:05Z
dc.date.available
2021-04-07T08:02:59Z
dc.date.issued
2017-09-01
dc.identifier.issn
0001-1541
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dc.description.abstract
Knowing the conditions for a system to undergo thermal explosion is of utmost importance for many applications. A critical condition that accounts for reactant consumption and covers most practical situations, including low activation energy reactions is presented. Our solution applies to cylindrical reactors of any radius to height ratio. In the case of films, it is shown that thermal explosion is virtually impossible. A new criterion to define the boundary of thermal run- away based on heat balance is introduced. This new definition of criticality allows us to check the accuracy of the non- stationary model to describe the critical condition. The nonstationary model is the base of most approaches
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15 p.
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application/pdf
dc.language.iso
eng
dc.publisher
Wiley
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Versió postprint del document publicat a: https://doi.org/10.1002/aic.15727
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© AIChE Journal, 2017, vol. 63, núm. 9, p. 3979-3993
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Articles publicats (D-F)
dc.rights
Tots els drets reservats
dc.source
Sánchez-Rodríguez, Daniel Farjas Silva, Jordi Roura Grabulosa, Pere 2017 The critical condition for thermal explosion in an isoperibolic system AIChE Journal 63 9 3979 3993
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dc.title
The critical condition for thermal explosion in an isoperibolic system
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.embargo.terms
2018-09-01
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2018-09-01
dc.type.version
info:eu-repo/semantics/acceptedVersion
dc.identifier.doi
dc.identifier.idgrec
027168
dc.identifier.eissn
1547-5905