M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers

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Oleshkevich, Elena
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Viñas, Clara
orcId Romero García, Isabel​ researcherId Romero García, Isabel​ scopusId Romero García, Isabel​ ​
Romero García, Isabel
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Choquesillo Lazarte, Duane
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Haukka, Matti
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Teixidor Bombardó, Francesc
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The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied ​
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