Model Csp2-Csp3 Hurtley Coupling Catalysis that Operates through a Well-Defined CuI/CuIII Mechanism
dc.contributor.author
dc.date.accessioned
2017-05-31T11:03:50Z
dc.date.available
2017-05-31T11:03:50Z
dc.date.issued
2013-03
dc.identifier.issn
1867-3880
dc.identifier.uri
dc.description.abstract
Hurtley-type coupling reactions, which were first discovered
more than 80 years ago, involve the copper-catalyzed a-arylation
of activated methylene compounds by using aryl halide
substrates.[1–3] These reactions afford Csp2 Csp3 coupling products,
usually as their a-aryl ketone derivatives. These compounds
are important because they are found in a large
number of natural products and they have also found wide application
in pharmaceutical chemistry.[4] Importantly, there is
not a clear understanding of the mechanistic details of copperbased
Hurtley catalysis; therefore, unraveling the mechanistic
pathways is of fundamental importance to facilitate the design
of more-sustainable methodologie
dc.description.sponsorship
We acknowledge financial support from the European Research Council for a Starting Grant Project to X.R. (ERC-2011-StG-277801), the MICINN of Spain (CTQ2009-08464/BQU to Dr. Costas and a PhD FPI grant to M.F.), the Consolider-Ingenio (CSD2010-00065), and the Catalan DIUE of the Generalitat de Catalunya (2009SGR637)
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
MICINN/PN 2010-2012/ CTQ2009-08464
MICINN/PN 2010-2016/CSD2010-00065
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/cctc.201200885
dc.relation.ispartof
© ChemCatChem, 2013, vol. 5, núm. 3, p. 687-691
dc.relation.ispartofseries
Articles publicats (D-Q)
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Tots els drets reservats
dc.title
Model Csp2-Csp3 Hurtley Coupling Catalysis that Operates through a Well-Defined CuI/CuIII Mechanism
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/277801/EU/Sustainable C-X and C-H Functionalization Catalyzed by Copper(III) Species/SUSCATCU3
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
019152
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
1867-3899