Understanding Electronic Ligand Perturbation over Successive Metal-Based Redox Potentials in Mononuclear Ruthenium–Aqua Complexes
dc.contributor.author
dc.date.accessioned
2017-03-02T11:31:23Z
dc.date.available
2017-03-02T11:31:23Z
dc.date.issued
2013-03
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2192-6506
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dc.description.abstract
A family of new ruthenium complexes containing a combination of polypyridyl and carbene ligands has been prepared and characterized from structural, spectroscopic, and redox viewpoints both experimentally and computationally. Interestingly, a correlation between ΔE1/2, defined as the difference between E1/2(RuIV/III) and E1/2(RuIII/II), and the activity and selectivity of some catalytic oxidation processes has been clearly established. A density functional theory study on the synthesized species has been carried out revealing a correlation between the number of carbene ligands and ΔE1/2, and consequently with the RuIII disproportionation. The reactivity of these complexes has been tested with regard to the electrocatalytic oxidation of benzyl alcohol.
dc.description.sponsorship
Support from MINECO (CTQ2010-21497, CTQ2011-26440, CTQ2010-21532-C02-01, CTQ2009-08328, and CTQ2011-23121), “Torres y Quevedo” contract (X.S.) and Consolider Ingenio 2010 (CSD2006-0003) are gratefully acknowledged
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application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
info:eu-repo/grantAgreement/MICINN//CTQ2010-21497/ES/CATALIZADORES PARA LA FOTOSINTESIS ARTIFICIAL/
info:eu-repo/grantAgreement/MICINN//CTQ2010-21532-C02-01/ES/MIMETIZACION DE PROCESOS BIOINORGANICOS Y APLICACIONES CATALITICAS CON COMPUESTOS DE METALES DE TRANSICION./
info:eu-repo/grantAgreement/MICINN//CTQ2011-23121/ES/APLICACIONES CATALITICAS DE COMPUESTOS DE RODIO, PALADIO Y NIQUEL EN SINTESIS ORGANICA. METODOLOGIA Y ESTUDIOS MECANISTICOS./
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/cplu.201200268
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© ChemPlusChem, 2013, vol. 78, núm. 3, p. 235 – 243
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Articles publicats (D-Q)
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Tots els drets reservats
dc.subject
dc.title
Understanding Electronic Ligand Perturbation over Successive Metal-Based Redox Potentials in Mononuclear Ruthenium–Aqua Complexes
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
018608
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dc.relation.ProjectAcronym