DUGiDocsSimple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands
dc.contributor.author
dc.date.accessioned
2016-12-02T08:40:49Z
dc.date.available
2016-12-02T08:40:49Z
dc.date.issued
2016-01-28
dc.identifier.uri
dc.description.abstract
A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered
N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands. The innovative pre-catalysts were tested
regarding their behavior in ROMP and especially for their use in the synthesis of poly(dicyclopentadiene) (pDCPD). Bearing either
the common phosphine leaving ligand in the first and second Grubbs olefin metathesis catalysts, or the Ru–O bond cleavage for the
next Hoveyda-type catalysts, this work is a step forward towards the control of polymer functionalization and living or switchable
polymerizations
dc.description.sponsorship
A.P. thanks the Spanish MINECO for a project CTQ2014-59832-JIN, and European Commission for a Career Integration Grant (CIG09-GA-2011-293900
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Beilstein-Institut
dc.relation
info:eu-repo/grantAgreement/MINECO//CTQ2014-59832-JIN/ES/ESCANEO COMPUTACIONAL DE RELACIONES ESTRUCTURA%2FACTIVIDAD DE CATALIZADORES DE OXIDACION DEL AGUA PARA LA GENERACION DE H2/
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Reproducció digital del document publicat a: http://dx.doi.org/10.3762/bjoc.12.17
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Beilstein Journal of Organic Chemistry, 2016, vol. 12, p.154-165
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Articles publicats (D-Q)
dc.rights
Attribution 4.0 Spain
dc.rights.uri
dc.subject
dc.title
Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.embargo.terms
Cap
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/293900/EU/Ab initio Statics and Molecular Dynamics Simulation of Olefin Metathesis Catalysts for pharmacological purposes/COMPUTEDRUG
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
025565
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
1860-5397