DUGiDocsA biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature
dc.contributor.author
dc.date.accessioned
2016-03-15T12:09:05Z
dc.date.available
2016-03-15T12:09:05Z
dc.date.issued
2011
dc.identifier.issn
1433-7851
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dc.description
El mateix article està publicat en alemany a l'edició alemanya d' 'Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2011, vol. 123, núm. 6, p.1461–1465. DOI http://dx.doi.org/10.1002/ange.201004623
dc.description.abstract
It's no sacrifice: A bio-inspired iron system, in which a β-keto ester serves as a sacrificial cosubstrate, readily epoxidizes olefins under ambient conditions with air. Aromatic olefins are oxidized in high yields with excellent chemoselectivity. Mechanistic investigations point out substantial differences to well-known radical-based autoxidations
dc.description.sponsorship
M.C. thanks MICINN for project CTQ2009-08464/BQU, Generalitat de Catalunya for an ICREA Academia Award, and UdG STR for experimental support
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
MICINN/PN 2010-2012/ CTQ2009-08464
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.201004623
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© Angewandte Chemie International Edition, 2011, vol. 50, núm. 6, p. 1425-1429
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Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.subject
dc.title
A biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
013376
dc.contributor.funder
dc.identifier.eissn
1521-3773