DUGiDocsAn iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites
dc.contributor.author
dc.date.accessioned
2016-03-15T11:52:44Z
dc.date.available
2016-03-15T11:52:44Z
dc.date.issued
2013
dc.identifier.issn
0947-6539
dc.identifier.uri
dc.description.abstract
Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C[BOND]H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C[BOND]H bonds (see scheme)
dc.description.sponsorship
Financial support by the European Research Council for project ERC-29910, the MCYT of Spain through project CTQ200908464/BQU to M.C., and Consolider Ingenio/CSD2010-00065. I.P. and M.C thank the MICINN and Generalitat de Catalunya, respectively, for Ph.D. grants. M.C. and X.R. thank the Generalitat de Catalunya for 2009SGR637 and ICREA Acad mia Awards. Catexcel is acknowledged for a generous gift of tritosyltriazacyclononane
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
MICINN/PN 2010-2016/CSD2010-00065
MICINN/PN 2010-2012/ CTQ2009-08464
AGAUR/2009-2014/2009 SGR-637
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/chem.201203281
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© Chemistry-A European Journal, 2013, vol. 19, núm. 6, p. 1908-1913
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Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.subject
dc.title
An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
017181
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
1521-3765