DUGiDocsO2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper m-h1:h1 -Peroxido Complex
dc.contributor.author
dc.date.accessioned
2016-03-15T09:07:00Z
dc.date.available
2016-03-15T09:07:00Z
dc.date.issued
2010
dc.identifier.issn
1433-7851
dc.identifier.uri
dc.description
El mateix article està publicat en alemany a l'edició alemanya d' 'Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2010, vol. 122, núm. 13, p.2456–2459. DOI http://dx.doi.org/10.1002/ange.200906749
dc.description.abstract
Unusual reactivity: A novel unsymmetric dicopper complex gives rise to the unsymmetric species 1-O2 having a μ-η1:η1-O2 binding mode and reactivity patterns not previously observed for symmetric analogues. It is unreactive in oxygen atom transfer reactions, but it can selectively bind phenolate and mediate its ortho hydroxylation, thereby demonstrating a conceptually different tyrosinase model with exquisite selectivity
dc.description.sponsorship
This work was supported financially by MCYT of Spain (projects CTQ2006-05367/BQU and CTQ2009-08464/BQU to M.C.), by the U.S. NIH (grant GM38767 to L.Q.), and by the Italian MIUR (Prin project to L.L.). I.G.B and A.C. thank MICINN for PhD grants. M.T.- S. thanks the CSIC for the JAE-DOC contract. We thank STR-UdG for technical support. M.C. also thanks the Generalitat Catalunya for an ICREA-Academia award and for project 2009 SGR-637
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
MICINN/PN 2010-2012/CTQ2009-08464
MEC/PN 2006-2009/CTQ2006-05367
AGAUR/2009-2014/2009 SGR-637
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.200906749
dc.relation.ispartof
© Angewandte Chemie International Edition, 2010, vol. 49. núm. 13, p. 2406-2409
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Articles publicats (D-Q)
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Tots els drets reservats
dc.title
O2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper m-h1:h1 -Peroxido Complex
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
012662
dc.contributor.funder
dc.identifier.eissn
1521-3773