O2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper m-h1:h1 -Peroxido Complex

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orcId Garcia Bosch, Isaac​ ​ scopusId Garcia Bosch, Isaac​ ​
Garcia Bosch, Isaac
orcId Company Casadevall, Anna​ researcherId Company Casadevall, Anna​ scopusId Company Casadevall, Anna​ ​
Company Casadevall, Anna
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Frisch, Jonathan R.
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Torrent Sucarrat, Miquel
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Cardellach, Mar
orcId Gamba, Ilaria​ researcherId Gamba, Ilaria​ ​ ​
Gamba, Ilaria
​ ​ scopusId Güell Serra, Mireia​ ​
Güell Serra, Mireia
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Casella, Luigi
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Que, Lawrence
orcId Ribas Salamaña, Xavi​ ​ scopusId Ribas Salamaña, Xavi​ ​
Ribas Salamaña, Xavi
orcId Luis Luis, Josep Maria​ researcherId Luis Luis, Josep Maria​ scopusId Luis Luis, Josep Maria​ ​
Luis Luis, Josep Maria
orcId Costas Salgueiro, Miquel​ researcherId Costas Salgueiro, Miquel​ scopusId Costas Salgueiro, Miquel​ ​
Costas Salgueiro, Miquel
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Unusual reactivity: A novel unsymmetric dicopper complex gives rise to the unsymmetric species 1-O2 having a μ-η1:η1-O2 binding mode and reactivity patterns not previously observed for symmetric analogues. It is unreactive in oxygen atom transfer reactions, but it can selectively bind phenolate and mediate its ortho hydroxylation, thereby demonstrating a conceptually different tyrosinase model with exquisite selectivity ​
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