DUGiDocsSpectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
dc.contributor.author
dc.date.accessioned
2016-03-14T12:23:25Z
dc.date.available
2016-03-14T12:23:25Z
dc.date.issued
2016-01-01
dc.identifier.issn
1433-7851
dc.identifier.uri
dc.description
El mateix article està publicat a l'edició alemanya de la revista 'Angewandte chemie' (issn 0044-8249, eissn 1521-3757), 2016, vol. 128, núm.11, p. 3701–3705. DOI http://dx.doi.org/10.1002/ange.201511374
dc.description.abstract
Closely structurally related triplet and quintet iron(IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen-transfer and oxygen-transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass-selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin state
dc.description.sponsorship
This research was supported by the European Research Council (StG ISORI and BIDECASEOX), the Grant agency
of the Czech Republic (14-20077S), the Spanish MINECO (CTQ2012-37420-C02-01/BQU), and an ICREA Academia
Award to M.C. Computational resources were provided by the MetaCentrum under the program LM2010005 and the
CERIT-SC under the program Centre CERIT Scientific Cloud, part of the Operational Program Research and Development for Innovations, Reg. no. CZ.1.05/3.2.00/08.0144
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01/ES/DISEÑO BIOINSPIRADO DE CATALIZADORES PARA LA OXIDACION DE ENLACES C-H, C=C Y AGUA/
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.201511374
dc.relation.ispartof
Angewandte Chemie International Edition, 2016, vol. 55, núm. 11, p. 3637-3641
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Articles publicats (D-Q)
dc.rights
Attribution-NonCommercial 3.0 Spain
dc.rights.uri
dc.subject
dc.title
Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.embargo.terms
Cap
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
024587
dc.contributor.funder
dc.relation.ProjectAcronym
dc.identifier.eissn
1521-3773