DUGiDocsSerendipitous metal-catalyzed H-H/Si-H exchange
dc.contributor.author
dc.date.accessioned
2015-11-04T07:36:50Z
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2015-11-04T07:36:50Z
dc.date.issued
2014
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1434-1948
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dc.description.abstract
Various metal complexes catalyze exchange between H-2 and hydrosilanes. Catalyst screening suggests that the electron deficiency of the metal center is necessary for exchange, but silane and/or hydrogen addition or sigma-bond metathesis with the M-Si and M-H bonds are not required. Kinetic measurements for the system [(ArN=)Mo(PMe3)(3)(H)(SiH2Ph)/H-2/H3SiPh] (Ar = 2,6-iPr(2)C(6)H(3)) suggest that the reaction proceeds through activation of the silane
dc.description.sponsorship
his work was supported by Natural Sciences and Engineering Research Council of Canada (NSERC) (Discovery Grant to G. I. N.) and the Spanish Ministerio de Ciencia e Innovacion (MICINN) (grant number CTQ2011-23156/BQU)
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application/pdf
dc.language.iso
eng
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Wiley-VCH Verlag
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info:eu-repo/grantAgreement/MICINN//CTQ2011-23156/ES/AVANCES EN CATALISIS Y AROMATICIDAD/
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/ejic.201402202
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© European Journal of Inorganic Chemistry, 2014, vol. 18, p. 2896-2901
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Articles publicats (D-Q)
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Tots els drets reservats
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dc.title
Serendipitous metal-catalyzed H-H/Si-H exchange
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
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info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
022140
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dc.relation.ProjectAcronym
dc.identifier.eissn
1099-0682