Serendipitous metal-catalyzed H-H/Si-H exchange

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Nikonov, Georgii I.
orcId Vyboishchikov, Sergei F.​ ​ scopusId Vyboishchikov, Sergei F.​ ​
Vyboishchikov, Sergei F.
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Shirobokov, Oleg G.
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Simionescu, Razvan
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Various metal complexes catalyze exchange between H-2 and hydrosilanes. Catalyst screening suggests that the electron deficiency of the metal center is necessary for exchange, but silane and/or hydrogen addition or sigma-bond metathesis with the M-Si and M-H bonds are not required. Kinetic measurements for the system [(ArN=)Mo(PMe3)(3)(H)(SiH2Ph)/H-2/H3SiPh] (Ar = 2,6-iPr(2)C(6)H(3)) suggest that the reaction proceeds through activation of the silane ​
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