DUGiDocsDendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: Unprecedented enhancement of enantiodiscrimination
dc.contributor.author
dc.date.accessioned
2015-10-20T09:30:23Z
dc.date.available
2015-10-20T09:30:23Z
dc.date.issued
2012
dc.identifier.issn
1359-7345
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dc.description.abstract
Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(i) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds
dc.description.sponsorship
We would like to thank the Spanish MICINN (project CTQ2011-23121), the Generalitat de Catalunya (project 2009SGR637) and the CNRS (France) for their financial support. L. G. thanks the Universitat de Girona (UdG) for a predoctoral fellowship
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application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry (RSC)
dc.relation
info:eu-repo/grantAgreement/MICINN//CTQ2011-23121/ES/APLICACIONES CATALITICAS DE COMPUESTOS DE RODIO, PALADIO Y NIQUEL EN SINTESIS ORGANICA. METODOLOGIA Y ESTUDIOS MECANISTICOS./
AGAUR/2009-2014/2009 SGR-637
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Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c2cc32992a
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© Chemical Communications, 2012, vol. 48, núm. 74, p. 9248-9250
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Articles publicats (D-Q)
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Tots els drets reservats
dc.subject
dc.title
Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: Unprecedented enhancement of enantiodiscrimination
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
017627
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dc.relation.ProjectAcronym
dc.identifier.eissn
1364-548X