Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: Unprecedented enhancement of enantiodiscrimination

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Garcia López, Lídia
orcId Roglans i Ribas, Anna​ researcherId Roglans i Ribas, Anna​ scopusId Roglans i Ribas, Anna​ ​
Roglans i Ribas, Anna
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Laurent, Régis
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Majoral, Jean Pierre
orcId Pla i Quintana, Anna​ researcherId Pla i Quintana, Anna​ scopusId Pla i Quintana, Anna​ ​
Pla i Quintana, Anna
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Caminade, Anne Marie
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Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(i) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds ​
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