DUGiDocsA latent ruthenium based olefin metathesis catalyst with a sterically demanding NHC ligand
dc.contributor.author
dc.date.accessioned
2015-05-05T15:37:01Z
dc.date.available
2015-05-05T15:37:01Z
dc.date.issued
2012
dc.identifier.issn
2044-4753
dc.identifier.uri
dc.description.abstract
An olefin metathesis catalyst featuring a SIPr NHC and an ester chelating carbene ligand is introduced. In contrast to its previously published SIMes analogue, only the trans dichloro configurated isomer was obtained. The two counterparts are tested in various olefin metathesis reactions, revealing a striking superiority of the new complex in the cross metathesis of olefins with methyl vinyl ketone allowing for full conversion with only 500 ppm catalyst loading
dc.description.sponsorship
Financial support of this work from the Higher Education Commission of Pakistan (for M. A.) and the European Community (CP-FP 211468-2 EUMET) is gratefully acknowledged. A. P. thanks the Spanish MINECO for a Ramon y Cajal contract (ref. RYC-2009-05226) and the European Commission for a Career Integration Grant (CIG09-GA-2011-293900)
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry (RSC)
dc.relation
info:eu-repo/grantAgreement/MICINN//RYC-2009-05226/ES/RYC-2009-05226/
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c2cy20311a
dc.relation.ispartof
© Catalysis Science and Technology, 2012, vol. 8, núm. 2, p., 1640-1643
dc.relation.ispartofseries
Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.title
A latent ruthenium based olefin metathesis catalyst with a sterically demanding NHC ligand
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/293900/EU/Ab initio Statics and Molecular Dynamics Simulation of Olefin Metathesis Catalysts for pharmacological purposes/COMPUTEDRUG
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
020487
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
2044-4761