The role of organometallic copper (III) complexes in homogeneous catalysis
dc.contributor.author
dc.date.accessioned
2015-03-25T09:21:07Z
dc.date.available
2015-03-25T09:21:07Z
dc.date.issued
2013
dc.identifier.issn
2041-6520
dc.identifier.uri
dc.description.abstract
Organometallic CuIII species have been invoked in many copper-catalyzed reactions, but until recently, experimental evidences were lacking. The advent of new spectroscopic techniques and the characterization of simple and stable catalyst models have been key to gain clear mechanistic insights into these important reactions. In this perspective, we will discuss these discoveries and the corresponding mechanistic proposals that derive from important reactions such as nucleophilic organocuprate chemistry for C-C bond formation, C-heteroatom cross-coupling reactions (Ullmann condensation reactions and halide-exchange processes) and direct C-H bond functionalizations catalyzed by copper
dc.description.sponsorship
We acknowledge financial support from European Research Council for Starting Grant Project ERC-2011-StG-277801 to X. R., MICINN of Spain (INNPLANTA project INP-2011-0059-PCT-420000-ACT1 to X. R., CTQ2009-08464/BQU to Dr M. Costas and PhD FPU grant to A. C.), Consolider-Ingenio CSD2010-00065, and the Catalan DIUE of the Generalitat de Catalunya (2009SGR637). X. R. thanks ANC for guiding us to freedom and also thanks an ICREA-Academia award
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry (RSC)
dc.relation
MICINN/PN 2010-2012/CTQ2009-08464
MICINN/PN 2010-2016/CSD2010-00065
AGAUR/2009-2014/2009 SGR-637
MICINN/PN 2011/INP-2011-0059-PCT-420000
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c3sc21818j
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© Chemical Science, 2013, vol. 4, p. 2301-2318
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Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.subject
dc.title
The role of organometallic copper (III) complexes in homogeneous catalysis
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/277801/EU/Sustainable C-X and C-H Functionalization Catalyzed by Copper(III) Species/SUSCATCU3
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
018649
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
2041-6539