DUGiDocsChemical bonding in supermolecular flowers
dc.contributor.author
dc.date.accessioned
2015-03-24T13:03:49Z
dc.date.available
2015-03-24T13:03:49Z
dc.date.issued
2012
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1463-9076
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dc.description.abstract
We report here a systematic study on the ability of molecular cages to bind (transition) metals. Starting from the superferrocenophane we investigate the incorporation of first-row transition metal (Sc-Zn) and alkaline-earth metal (Mg, Ca) double cations into these supermetallocenophane (super[5]phane) cages, and compare them with the corresponding metallocenes (Inorg. Chim. Acta, 2007, 360, 179). Moreover, we also investigate the binding of neutral and double-cationic metals inside supermetallocyclophane (super[6]phane) cages. The heterolytic and homolytic associations show preferences for different metals, and new metal-containing cages are proposed that should be viable candidates for synthesis
dc.description.sponsorship
The following organizations are thanked for financial support: the Ministerio de Ciencia e Innovacion (MICINN, project number CTQ2011-25086/BQU), and the DIUE of the Generalitat de Catalunya (project number 2009SGR528). Financial support from MICINN (Ministry of Science and Innovation, Spain) and the FEDER fund (European Fund for Regional Development) was provided by grant UNGI08-4E-003. The authors are grateful to the Research Executive Agency of the European Research Council for financial support through the PIRSES-GA-2009-247671 project of the FP7-PEOPLE-2009-IRSES program. MPJ acknowledges support from the Ministerio de Ciencia e Innovacion (project JCI-2009-05953) and the Academy of Finland (project 136079). This work was supported in Guanajuato by Conacyt (Grant 57892); ACC thanks Conacyt for the Master fellowship
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry (RSC)
dc.relation
info:eu-repo/grantAgreement/MICINN//CTQ2011-25086/ES/MODELIZACION MULTIESCALAR EN (BIO)QUIMICA/
AGAUR/2009-2014/2009 SGR-528
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Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c2cp42045g
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© Physical Chemistry Chemical Physics, 2012, vol. 14, p. 14905-14910
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Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.title
Chemical bonding in supermolecular flowers
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/247671/EU/Chemical bonding and aromaticity in novel inorganic and organometallic clusters/CANIOC
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
016717
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dc.relation.FundingProgramme
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dc.identifier.eissn
1463-9084