DUGiDocsIron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
dc.contributor.author
dc.date.accessioned
2012-11-27T08:40:24Z
dc.date.available
2012-11-27T08:40:24Z
dc.date.issued
2012
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0947-6539
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dc.description.abstract
Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+
dc.description.sponsorship
Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910
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application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag Berlin
dc.relation
MICYT/CTQ2009-08864
MICINN/PN 2010-2016/CSD2010-00065
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/chem.201202147
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© Chemistry : a European Journal, 2012, vol. 18, núm. 42, p. 13269-13273
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Articles publicats (D-Q)
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Tots els drets reservats
dc.subject
dc.title
Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
1521-3765