Selective C–H oxidation catalyzed by metalloporphyrins

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Show simple item record Costas Salgueiro, Miquel 2011
dc.identifier.issn 0010-8545
dc.description.abstract Selective oxidation of saturated C–H bonds remains a challenge in modern chemistry. The inert nature of such bonds requires the use of highly reactive reagents, and this poses major challenges in terms of chemo, regio and stereoselectivity. Metalloporphyrins based in iron, manganese and ruthenium constitute a unique family of catalysts capable of generating these highly reactive, but at the same time highly selective oxidants, thus exquisitely mediating selective oxidations of C–H bonds. The mechanisms underlying these reactions are collected and discussed in the present work. Recent advances in the application of these catalysts in the oxidation of complex organic molecules are also reviewed
dc.description.sponsorship Financial support for this work was provided by MEC-Spain (Project CTQ2009-08464), Generalitat de Catalunya (2009SGR637), and European Research Council for project ERC-2009-StG-239910. M.C. acknowledges an ICREA-Academia Award. Anna Company, Laura Gomez and Dr Julio Lloret are acknowledged by a critical reading of the manuscript
dc.format.mimetype application/pdf
dc.language.iso eng
dc.relation MICINN/PN 2010-2012/CTQ2009-08464
dc.relation AGAUR/2009-2014/2009 SGR-637
dc.relation.isformatof Reproducció digital del document publicat a:
dc.relation.ispartof © Coordination Chemistry Reviews, 2011, vol. 255, Inúm. 23–24, p 2912–2932
dc.relation.ispartofseries Articles publicats (D-Q)
dc.rights Tots els drets reservats
dc.subject Reaccions químiques
dc.subject Chemical reactions
dc.subject Oxidació
dc.subject Oxidation
dc.subject Catalitzadors metàl·lics
dc.subject Metal catalysts
dc.title Selective C–H oxidation catalyzed by metalloporphyrins
dc.type info:eu-repo/semantics/article
dc.rights.accessRights info:eu-repo/semantics/closedAccess
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/239910
dc.type.version info:eu-repo/semantics/publishedVersion
dc.contributor.funder Ministerio de Ciencia e Innovación (Espanya)
dc.contributor.funder Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca

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