Selective C–H oxidation catalyzed by metalloporphyrins

DSpace/Manakin Repository

Show simple item record

dc.contributor.author Costas Salgueiro, Miquel
dc.date.issued 2012-10-15
dc.identifier.issn 0010-8545
dc.identifier.uri http://hdl.handle.net/10256/7136
dc.description.abstract Selective oxidation of saturated C–H bonds remains a challenge in modern chemistry. The inert nature of such bonds requires the use of highly reactive reagents, and this poses major challenges in terms of chemo, regio and stereoselectivity. Metalloporphyrins based in iron, manganese and ruthenium constitute a unique family of catalysts capable of generating these highly reactive, but at the same time highly selective oxidants, thus exquisitely mediating selective oxidations of C–H bonds. The mechanisms underlying these reactions are collected and discussed in the present work. Recent advances in the application of these catalysts in the oxidation of complex organic molecules are also reviewed
dc.format.mimetype application/pdf
dc.language.iso eng
dc.relation.isformatof Reproducció digital del document publicat a: http://dx.doi.org/10.1016/j.ccr.2011.06.026
dc.relation.ispartof © Coordination Chemistry Reviews, 2011, vol. 255, Inúm. 23–24, p 2912–2932
dc.relation.ispartofseries Articles publicats (D-Q)
dc.rights Tots els drets reservats
dc.subject Reaccions químiques
dc.subject Chemical reactions
dc.subject Oxidació
dc.subject Oxidation
dc.subject Catalitzadors metàl·lics
dc.subject Metal catalysts
dc.title Selective C–H oxidation catalyzed by metalloporphyrins
dc.type info:eu-repo/semantics/article
dc.rights.accessRights info:eu-repo/semantics/closedAccess
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/239910
dc.type.version info:eu-repo/semantics/publishedVersion
dc.identifier.doi http://dx.doi.org/10.1016/j.ccr.2011.06.026


Files in this item

 

Show simple item record

Related Items

Search DUGiDocs


Browse

My Account

Statistics

Impact

This file is restricted

The file you are attempting to access is a restricted file and requires credentials to view. Please login below to access the file.

  1. We will contact you via the email address you have provided us.