Well-Defined Heterometallic and Unsymmetric M2O2 Complexes Arising from Binding and Activation of O2

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dc.contributor.author Garcia Bosch, Isaac
dc.contributor.author Ribas Salamaña, Xavi
dc.contributor.author Costas Salgueiro, Miquel
dc.date.issued 2012
dc.identifier.issn 1099-0682
dc.identifier.uri http://hdl.handle.net/10256/7126
dc.description.abstract Oxygen binding and activation reactions at dimetal sites constitute chemical processes of fundamental interest, because of the implication of these reactions in biology, chemical synthesis, and catalysis. This account collects and discusses studies of O2 binding and/or activation by inequivalent dimetal sites, and it specially focuses on systems in which O2-bound reaction intermediates have been experimentally characterized. Homometallic unsymmetric systems and heterometallic complexes are reviewed, and their chemistry in oxidative transformations is described. Introduction of asymmetry into M2O2 cores poses important challenges to their preparation, and strategies developed to address this problem are discussed. Distinct spectroscopic and chemical properties emerge from these unsymmetric systems
dc.description.sponsorship We thank Dr. A. Company for fruitful discussions. I. G.-B. thanks the Ministerio de Ciencia e Innovacion (MICINN) for a PhD grant. M. C. and X. R. acknowledge financial support by Institucio Catalana de Recerca i Estudis Avancats (ICREA-Academia), Generalitat de Catalunya (2009-SGR637), Ministerio de Ciencia e Innovacion (MICINN), Spain (CTQ2009-08464/BQU), the European Research Council (project ERC-2009-StG-239910), and Consolider Ingenio (CSD2010-00065)
dc.format.mimetype application/pdf
dc.language.iso eng
dc.relation MICINN/PN 2010-2012/CTQ2009-08464
dc.relation MICINN/PN 2010-2016/CSD2010-00065
dc.relation AGAUR/2009-2014/2009 SGR-637
dc.relation.isformatof Reproducció digital del document publicat a: http://dx.doi.org/10.1002/ejic.201100957
dc.relation.ispartof © European Journal of Inorganic Chemistry, 2012, núm. 2, p. 179-187
dc.relation.ispartofseries Articles publicats (D-Q)
dc.rights Tots els drets reservats
dc.subject Oxigen actiu
dc.subject Active oxygen
dc.subject Química bioorgànica
dc.subject Bioorganic chemistry
dc.subject Compostos de coordinació
dc.subject Coordination compounds
dc.title Well-Defined Heterometallic and Unsymmetric M2O2 Complexes Arising from Binding and Activation of O2
dc.type info:eu-repo/semantics/article
dc.rights.accessRights info:eu-repo/semantics/closedAccess
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/239910
dc.type.version info:eu-repo/semantics/publishedVersion
dc.identifier.doi http://dx.doi.org/10.1002/ejic.201100957
dc.contributor.funder Ministerio de Ciencia e Innovación (Espanya)
dc.contributor.funder Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca

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