Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes

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Show simple item record Garcia Bosch, Isaac Gómez Martín, Laura Polo Ortiz, Alfonso Ribas Salamaña, Xavi Costas Salgueiro, Miquel 2012
dc.identifier.issn 1615-4169
dc.description.abstract Novel manganese complexes containing N4-tetradentate ligands derived from chiral bipyrrolidinediamines catalyze the stereoselective epoxidation of a wide array of alkenes using low catalyst loadings (0.1 mol%) and hydrogen peroxide (1.2 equiv.) as terminal oxidant. This family of catalysts affords good to excellent yields (80–100%) and moderate to good ees (40–73%) in short reaction times (30 min) making efficient use of hydrogen peroxide
dc.description.sponsorship M.C. thanks MICINN (CTQ2009-08464/BQU and PhD grants to I.G.-B.) and the European Research Council (ERC-StG-239910). M. C. and X. R. acknowledge ICREA-Academia Awards, and SGR 2009-SGR637
dc.format.mimetype application/pdf
dc.language.iso eng
dc.relation MICINN/PN 2010-2012/CTQ2009-08464
dc.relation AGAUR/2009-2014/2009 SGR-637
dc.relation.isformatof Reproducció digital del document publicat a:
dc.relation.ispartof © Advanced Synthesis & Catalysis, 2012, vol. 354, núm. 1, p. 65-70
dc.relation.ispartofseries Articles publicats (D-Q)
dc.rights Tots els drets reservats
dc.subject Manganès -- Compostos -- Oxidació
dc.subject Manganese compounds -- Oxidation
dc.subject Catalitzadors
dc.subject Catalysts
dc.subject Aigua oxigenada
dc.subject Hydrogen peroxide
dc.subject Reaccions químiques
dc.subject Chemical reactions
dc.title Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes
dc.type info:eu-repo/semantics/article
dc.rights.accessRights info:eu-repo/semantics/closedAccess
dc.relation.projectID info:eu-repo/grantAgreement/EC/FP7/239910
dc.type.version info:eu-repo/semantics/publishedVersion
dc.contributor.funder Ministerio de Ciencia e Innovación (Espanya)
dc.contributor.funder Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca

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