Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes

dc.contributor.author	Garcia Bosch, Isaac
dc.contributor.author	Gómez Martín, Laura
dc.contributor.author	Polo Ortiz, Alfonso
dc.contributor.author	Ribas Salamaña, Xavi
dc.contributor.author	Costas Salgueiro, Miquel
dc.date.issued	2012-10-09
dc.identifier.issn	1615-4169
dc.identifier.uri	http://hdl.handle.net/10256/7122
dc.description.abstract	Novel manganese complexes containing N4-tetradentate ligands derived from chiral bipyrrolidinediamines catalyze the stereoselective epoxidation of a wide array of alkenes using low catalyst loadings (0.1 mol%) and hydrogen peroxide (1.2 equiv.) as terminal oxidant. This family of catalysts affords good to excellent yields (80–100%) and moderate to good ees (40–73%) in short reaction times (30 min) making efficient use of hydrogen peroxide
dc.format.mimetype	application/pdf
dc.language.iso	eng
dc.relation.isformatof	http://dx.doi.org/10.1002/adsc.201100409
dc.relation.ispartof	© Advanced Synthesis & Catalysis, 2012, vol. 354, núm. 1, p. 65-70
dc.relation.ispartofseries	Articles publicats (D-Q)
dc.rights	Tots els drets reservats
dc.subject	Manganès -- Compostos -- Oxidació
dc.subject	Manganese compounds -- Oxidation
dc.subject	Catalitzadors
dc.subject	Catalysts
dc.subject	Aigua oxigenada
dc.subject	Hydrogen peroxide
dc.subject	Reaccions químiques
dc.subject	Chemical reactions
dc.title	Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes
dc.type	info:eu-repo/semantics/article
dc.rights.accessRights	info:eu-repo/semantics/closedAccess
dc.relation.projectID	info:eu-repo/grantAgreement/EC/FP7/239910
dc.type.version	info:eu-repo/semantics/publishedVersion