DUGiDocsStereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes
dc.contributor.author
dc.date.accessioned
2012-10-09T11:27:38Z
dc.date.available
2012-10-09T11:27:38Z
dc.date.issued
2012
dc.identifier.uri
dc.description.abstract
Novel manganese complexes containing N4-tetradentate ligands derived from chiral bipyrrolidinediamines catalyze the stereoselective epoxidation of a wide array of alkenes using low catalyst loadings (0.1 mol%) and hydrogen peroxide (1.2 equiv.) as terminal oxidant. This family of catalysts affords good to excellent yields (80–100%) and moderate to good ees (40–73%) in short reaction times (30 min) making efficient use of hydrogen peroxide
dc.description.sponsorship
M.C. thanks MICINN (CTQ2009-08464/BQU and PhD grants to I.G.-B.) and the European Research Council (ERC-StG-239910). M. C. and X. R. acknowledge ICREA-Academia Awards, and SGR 2009-SGR637
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.relation
MICINN/PN 2010-2012/CTQ2009-08464
AGAUR/2009-2014/2009 SGR-637
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/adsc.201100409
dc.relation.ispartof
© Advanced Synthesis & Catalysis, 2012, vol. 354, núm. 1, p. 65-70
dc.relation.ispartofseries
Articles publicats (D-Q)
dc.rights
Tots els drets reservats
dc.subject
dc.title
Stereoselective Epoxidation of Alkenes with Hydrogen Peroxide using a Bipyrrolidine-Based Family of Manganese Complexes
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
1615-4169