DUGiDocsSelective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds
dc.contributor.author
dc.date.accessioned
2017-05-30T11:31:44Z
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2017-05-30T11:31:44Z
dc.date.issued
2016-10-14
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2155-5435
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dc.description.abstract
The search for a low-cost process for the valorization of linear α-olefins combining high productivity and high selectivity is a longstanding goal for chemists. Herein, we report a soluble ruthenium olefin metathesis catalyst that performs the conversion of linear α-olefins to longer internal linear olefins with high selectivity (>99%) under neat conditions at low loadings (50 ppm) and without the need of expensive additives. This robust catalytic process allowed us to efficiently and selectively re-equilibrate the naphtha fraction (C5–C8) of a Fischer–Tropsch feed derived from non-petroleum resources to a higher-value product range (C9–C14), useful as detergent and plasticizer precursors
dc.description.sponsorship
This work was supported by the European Community through the seventh framework program (CP-FP 211468-2 EUMET, grant to M.R., L.F., and E.B.). M.M. thanks the CNRS, the ENSCR, Rennes Métropole, and the Région-Bretagne for their financial support. A.P. thanks the Spanish MINECO for project CTQ2014- 59832-JIN, and L.C. acknowledges funding from the King Abdullah University of Science and Technology (KAUST)
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application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society (ACS)
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info:eu-repo/grantAgreement/MINECO//CTQ2014-59832-JIN/ES/ESCANEO COMPUTACIONAL DE RELACIONES ESTRUCTURA%2FACTIVIDAD DE CATALIZADORES DE OXIDACION DEL AGUA PARA LA GENERACION DE H2/
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Reproducció digital del document publicat a: http://dx.doi.org/10.1021/acscatal.6b01428
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© ACS Catalysis, 2016, vol. 6, núm. 11, p. 7970–7976
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Articles publicats (D-Q)
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Tots els drets reservats
dc.subject
dc.title
Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds
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info:eu-repo/semantics/article
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info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
026263
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