DUGiDocsBinding of ion pairs in a thiourea-functionalized self-folding cavitand
dc.contributor.author
dc.date.accessioned
2017-03-30T08:17:12Z
dc.date.available
2017-03-30T08:17:12Z
dc.date.issued
2017-03-21
dc.identifier.issn
2052-4110
dc.identifier.uri
dc.description.abstract
We report the synthesis of a new synthetic cavitand receptor with an embedded thiourea moiety directed at effective molecular recognition of ion pairs. Initial prospects towards the use of cavitands in biomimetic carbocationic cyclizations have been carried out, employing ionic guests as stable surrogates for putative substrates and intermediates. The cavitand displays tight binding with tetramethylammonium salts, with unforeseen slow exchange kinetics of both cation and anion components
dc.description.sponsorship
We thank MINECO – Spanish Government (“Ramón y Cajal” grant to A. L. RYC2012-11112, CTQ2014-54306-P, and CTQ2014-61629-EXP), Generalitat de Catalunya, 2014SGR931, and Universitat de Girona (MPCUdG2016/096) for financial support
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry
dc.relation
info:eu-repo/grantAgreement/MINECO//CTQ2014-54306-P/ES/ESTUDIOS TEORICO-EXPERIMENTALES DE CICLACIONES CATALIZADAS POR METALES DE TRANSICION. NUEVOS DESARROLLOS EN AROMATICIDAD, FUNCIONALES DE LA DENSIDAD Y QUIMICA SUPRAMOLECULAR/
info:eu-repo/grantAgreement/MINECO//CTQ2014-61629-EXP/ES/SINTESIS ESPECIFICA DE NANOTUBOS DE CARBONO MEDIANTE FOTOCATALISIS CON LUZ VISIBLE./
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Reproducció digital del document publicat a: http://dx.doi.org/10.1039/C7QO00191F
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Organic chemistry frontiers : an international journal of organic chemistry, 2017, vol. 4, núm. 7, p. 1244-1249
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Articles publicats (D-Q)
dc.rights
Attribution-NonCommercial 3.0 Spain
dc.rights.uri
dc.subject
dc.title
Binding of ion pairs in a thiourea-functionalized self-folding cavitand
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.embargo.terms
Cap
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.contributor.funder
dc.relation.ProjectAcronym
dc.identifier.eissn
2052-4129