Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis
dc.contributor.author
dc.date.accessioned
2017-02-15T08:07:11Z
dc.date.available
2017-02-15T08:07:11Z
dc.date.issued
2017-01
dc.identifier.issn
2041-6520
dc.identifier.uri
dc.description.abstract
Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides
dc.description.sponsorship
This work was supported by grants from the European Research Council (Starting Grant Project ERC-2011-StG-277801), Spanish MINECO (CTQ2013-43012-P to XR, CTQ2015-64436-P to TP, Consolider-Ingenio CSD2010-00065 and INNPLANTA project INP-2011-0059-PCT-420000-ACT1) and Generalitat de Catalunya (2014 SGR 862)
dc.format.mimetype
application/pdf
dc.language.iso
eng
dc.publisher
Royal Society of Chemistry (RSC)
dc.relation
info:eu-repo/grantAgreement/MINECO//CTQ2013-43012-P/ES/INVESTIGACIONES MECANISTICAS PARA SINTESIS ORGANICA SOSTENIBLE VIA ACTIVACION DE PEQUEÑAS MOLECULAS GASEOSAS Y DE ENLACES C-H CON METALES DE LA PRIMERA SERIE DE TRANSICION/
dc.relation.isformatof
Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c6sc03699f
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© Chemical Science, 2017, vol. 8, núm. 2, p. 946-952
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Articles publicats (D-Q)
dc.rights
Attribution 3.0 Spain
dc.rights.uri
dc.subject
dc.title
Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/openAccess
dc.embargo.terms
Cap
dc.relation.projectID
info:eu-repo/grantAgreement/EC/FP7/277801/EU/Sustainable C-X and C-H Functionalization Catalyzed by Copper(III) Species/SUSCATCU3
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
026352
dc.contributor.funder
dc.relation.FundingProgramme
dc.relation.ProjectAcronym
dc.identifier.eissn
2041-6539